{ "cells": [ { "cell_type": "markdown", "metadata": {}, "source": [ "# 4.5 – Phase Diagrams\n", "\n", "---" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## 4.5.0 – Learning Objectives\n", "\n", "By the end of this section you should be able to:\n", "\n", "1. Understand what each line in a phase diagram represent.\n", "2. Understand what is in each region of a phase diagram.\n", "3. Understand what important points are on the phase diagram.\n", "4. Understand what the difference is between a vapour and gas.\n", "\n", "---" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## 4.5.1 – Introduction\n", "\n", "**Phase diagrams** are used to show all the phases of a substance at different pressures and temperatures. Each line represents phase equilibrium or boundaries.\n", "\n", "---" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## 4.5.2 – Diagram\n", "\n", "Shown bellow is a typical phase diagram.\n", "\n", "![](../figures/Module-4/Phase_Diagram1.png)\n", "\n", "Attribution: [[::User:Matthieumarechal|Matthieumarechal]] [GFDL (http://www.gnu.org/copyleft/fdl.html) or CC-BY-SA-3.0 (http://creativecommons.org/licenses/by-sa/3.0/)], via Wikimedia Commons\n", "\n", "The **red line** represents the boundary between a solid and a vapour. In this area, solid will directly turn to a vapour or a vapour will directly turn into a solid such as dry ice and $CO_2$. The **dotted green line** represents the boundary between a liquid and a solid for polar fluids such as water. Since ice is less dense than liquid water, it causes the dotted line to skew to the left. The **solid green line** represents the same thing as the **dotted green line** except for non-polar fluids. Finally, the **blue line** represents the boundary between a liquid and a vapour.\n", "\n", "Two main points of interest are the **triple point** and the **critical point**. The triple point is the point at which all three phases coexist at a certain pressure and temperature. The critical point is the point at which if you increase the pressure or temperature, a gas becomes indistinguishable from the liquid. The phase in this region is called a **supercritical fluid**.\n", "\n", "Another example of a phase diagram is shown below. This is the phase diagram of water.\n", "\n", "![](../figures/Module-4/Phase_diagram_of_water1.png)\n", "\n", "Attribution: By Cmglee (Own work) [CC BY-SA 3.0 (http://creativecommons.org/licenses/by-sa/3.0)], via Wikimedia Commons\n", "\n", "---" ] }, { "cell_type": "markdown", "metadata": {}, "source": [ "## 4.5.3 – Difference Between Vapour and Gas\n", "\n", "A substance is considered a **gas** when its temperature is **higher** than the critical temperature and below the critical pressure. A gas can not become a liquid by just increasing the pressure, you must also lower the temperature. \n", "\n", "A substance is considered a **vapour** when its temperature is **lower** than the critical temperature and below the critical pressure. A vapour can become a liquid by just increasing the pressure." ] }, { "cell_type": "markdown", "metadata": { "collapsed": true }, "source": [ "## 4.5.4 – Phase diagrams for ternary systems \n", "\n", "Partially miscible systems with 3 components can be represented in a ternary phase diagram. It's actually shaped like an equililateral triangle:\n", "\n" ] }, { "cell_type": "code", "execution_count": null, "metadata": { "collapsed": true }, "outputs": [], "source": [] } ], "metadata": { "anaconda-cloud": {}, "kernelspec": { "display_name": "Python 3", "language": "python", "name": "python3" }, "language_info": { "codemirror_mode": { "name": "ipython", "version": 3 }, "file_extension": ".py", "mimetype": "text/x-python", "name": "python", "nbconvert_exporter": "python", "pygments_lexer": "ipython3", "version": "3.6.1" } }, "nbformat": 4, "nbformat_minor": 2 }